Triazenolysis of alkenes as an aza version of ozonolysis
Nature Chemistry 2024
A. Koronatov, P. Sakharov, D. Ranolia, A. Kaushansky, N. Fridman, and M. Gandelman
Development of Modular Nitrenium Bipolar Electrolytes for Possible Applications in Symmetric Redox Flow Batteries
J. Am. Chem. Soc. 2024, 146, 28, 19474–19488
A. Varenikov, M. Gandelman, M. S. Sigman
Metal–Ligand Cooperative Catalytic Coupling of Terminal Alkynes and Carboxylic Acids for the Stereoselective Synthesis of Dienyl Esters
Organometallics 2024 43 (3), 368-380
A. Hassin, R. Levy, N. Fridman, and M. Gandelman
Nitrenium ions as new versatile reagents for electrophilic amination
Chem. Sci., 2023, 14, 12034-12040
I. Avigdori, K. Singh, N. Fridman and M. Gandelman
Multimodal Reactivity of N–H Bonds in Triazanes and Isolation of a Triazinyl Radical
J. Am. Chem. Soc. 2022, 144, 51, 23642–23648
A. Koronatov, A. Mauda, B. Tumansky, A. Kaushansky, N. Fridman, D. Bravo-Zhivotovskii, and M. Gandelman
Nitrenium Salts in Intramolecular Lewis Pairs
Z. Anorg. Allg. Chem. 2023, 649, e202200326. Invited article.
I. Avigdori, K. Singh, A. Pogoreltsev, A. Kaushansky, N. Fridman, M. Gandelman
Triazolium Salts as Lewis Acid Catalysts
Org. Lett. 2022, 24, 22, 3915–3919
D. Ranolia, I. Avigdori, K. Singh, A. Koronatov, N. Fridman, M. Gandelman
New Generation of Nitrenium Salts: Catalytic Hydrosilylation of Imines and a Mechanism of Action of Nitrogen Lewis Acids
ACS Catal. 2022, 12, 12, 6831–6839
K. Singh, I. Avigdori, A. Kaushansky, N. Fridman, D. Toledano, M. Gandelman
Decarboxylative Halogenation of Organic Compounds
Chem. Rev. 2021, 121, 412
A. Varenikov, E. Shapiro, M. Gandelman
Synthesis of Chiral α-CF3-Substituted Benzhydryls via Cross-Coupling Reaction of Aryltitanates
Org. Lett. 2020, 22, 23, 9386
A. Varenikov, E. Shapiro, M. Gandelman
Frustrated Lewis Pairs Comprising Nitrogen Lewis Acids for Si‐H Bond Activation
Angew. Chem. Int. Ed. 2020, 59, 23476
I. Avigdori, A. Pogoreltsev, A. Kaushanski, N. Fridman, M. Gandelman
O-Carboranylene versus Phenylene Backbones in Cyclization Reactions of 1,2 Diketones with Hydrosilanes
Organometallics 2020, 39, 4232
K. Jaiswal, K. Chulsky, M. Gandelman, R. Dobrovetsky
New P-chirogenic tert.-butyl-xantphos ligands and their application in asymmetric hydrogenation and alkylation
Tetrahedron 2020, 76, 17, 131142
J. Holz, G. Wenzel, A. Spannenberg, M. Gandelman, A. Börner
Direct Copper‐Catalyzed C‐H Monofluoroalkylation of Benzoxazoles with 1‑Fluoro‐1‐haloalkanes
Eur. J. Org. Chem. 2020, 21, 3138
W. Li, A. Varenikov, M. Gandelman
Bidentate Triazolate-Based Ligand System: Synthesis, Coordination Modes, and Cooperative Bond Activation
Organometallics 2020, 39, 3, 425
A. Hassin, N. Fridman, M. Gandelman
Organotitanium nucleophiles in asymmetric cross-coupling reaction: stereoconvergent synthesis of chiral α-fluoroalkyl thioethers
J. Am. Chem. Soc. 2019, 141, 10994
A. Varenikov, M. Gandelman
Synthesis and characteristics of iridium complexes bearing N-heterocyclic nitrenium cationic ligands
Organometallics 2019, 38, 2494
H. Levy-Vahav, A. Pogoreltsev, Y. Tulchinsky, N. Fridman, A. Börner, M. Gandelman
Synthesis of chiral α-trifluoromethyl alcohols and ethers via enantioselective Hiyama cross-couplings of bisfunctionalized electrophiles
Nature Commun. 2018, 9, 3566
A. Varenikov, M. Gandelman
About the Inversion Barriers of P‐Chirogenic Triaryl‐Substituted Phosphanes
Chem. Eur. J. 2018, 23, 2984
J. Holz, H. Jiao, M. Gandelman, A. Börner
Aliphatic C–H Bond Iodination by a N-Iodoamide and Isolation of an Elusive N-Amidyl Radical
J. Org. Chem. 2017, 82 (14), 7093
A. Artaryan, A. Mardyukov, K. Kulbitski, I. Avigdori, G. Nisnevich, P. Schreiner, M. Gandelman
Nitrogen Lewis Acids
J. Am. Chem. Soc. 2017, 139, 4062
A. Pogoreltsev, Y. Tulchinsky, N. Fridman, M. Gandelman
Enantioselective assembly of tertiary stereocenters via multicomponent chemoselective cross-coupling of geminal chloro (iodo) alkanes
Chem. Sci. 2016, 7, 2762
X. Jiang, K. Kulbitski, G. Nisnevich, M. Gandelman
Coordination Chemistry of N‐Heterocyclic Nitrenium‐Based Ligands
Chem.: Eur. J. 2015, 21, 6965
Y. Tulchinsky, S. Kozuch, P. Saha, A. Mauda, G. Nisnevich, M. Botoshansky, L. J. W. Shimon, M. Gandelman
Enantioselective Suzuki cross-couplings of unactivated 1-fluoro-1-haloalkanes: Synthesis of chiral β-, γ-, δ-, and ε-fluoroalkanes
J. Am. Chem. Soc. 2015, 137, 2542
X. Jiang, M. Gandelman
Efficient synthesis of secondary alkyl fluorides via Suzuki cross-coupling reaction of 1‑halo‑1‑fluoroalkanes
J. Am. Chem. Soc. 2014, 136, 9548
X. Jiang, S. Sakthivel, K. Kulbitski, G. Nisnevich, M. Gandelman
Cation–cation bonding in nitrenium metal complexes
Chem. Sci. 2014, 5, 1305
Y. Tulchinsky, S. Kozuch, P. Saha, M. Botoshansky, L. J. W. Shimon, M. Gandelman
Design and Development of Bioinspired Guanine‐Based Organic Catalyst for Asymmetric Catalysis
Eur. J. Org. Chem. 2012, 2118
G. Suez, V. Bloch, G. Nisnevich, M. Gandelman
Nitrenium ions as ligands for transition metals
Nat. Chem. 2011, 3, 525
Y. Tulchinsky, M. A. Iron, M. Botoshansky, M. Gandelman
Metal‐Free Efficient, General and Facile Iododecarboxylation Method with Biodegradable Co‐Products
Advanced Syn. & Cat. 2011, 353, 1438
K. Kulbitski, G. Nisnevich, M. Gandelman
Modifiable bidentate systems via N–C rearrangement in triazoles
Chem. Commun. 2011, 47, 319
E. A. S. Smith, G. Molev, M. Botoshansky, M. Gandelman
1, 2, 3-Triazolylidene based complexes via post-modification of pincer click ligands
Dalton Trans. 2011, 40, 8764
E. M. Schuster, M. Botoshansky, M. Gandelman
Azidomethyl Phenyl Sulfide
Encyclopedia of Reagents for Organic Synthesis, 2010, John Wiley & Sons
E. M. Schuster, M. Gandelman
Versatile, Selective, and Switchable Coordination Modes of Pincer Click Ligands
Organometallics 2009, 28, 7001
E. M. Schuster, M. Botoshansky, M. Gandelman
Synthesis of Novel Bulky, Electron-Rich Propargyl and Azidomethyl Dialkyl Phosphines and Their Use in the Preparation of Pincer Click Ligands
Organometallics 2009, 28, 5025
E. M. Schuster, G. Nisnevich, M. Botoshansky, M. Gandelman
Pincer click ligands
Angew. Chem. Int. Ed. 2008, 47, 4555
E. M. Schuster, M. Botoshansky, M. Gandelman
PAPERS BEFORE TECHNION
Stable Carbene and Diazoalkane Complexes of the Same Complex System. Synthesis, Structure, and Reactivity of PNP− Ru (II) Fluorenylidene and Diazofluorene Complexes
Organometallics 2008, 27, 3526
J. Zhang, M. Gandelman, L. J. W. Shimon, D. Milstein
Anionic d8 Alkyl Hydrides – Selective Formation and Reactivity of Anionic cis‐PtII Methyl Hydride
Eur. J. Org. Chem. 2010, 13, 1991
E. Poverenov, M. A. Iron, M. Gandelman, Y. Ben‐David, D. Milstein
Electron-rich, bulky PNN-type ruthenium complexes: synthesis, characterization and catalysis of alcohol dehydrogenation
Dalton Trans. 2007, 107
J. Zhang, M. Gandelman, L. J. W. Shimon, D. Milstein
ortho C−H Activation of Haloarenes and Anisole by an Electron-Rich Iridium(I) Complex: Mechanism and Origin of Regio- and Chemoselectivity. An Experimental and Theoretical Study
Organometallics 2006, 25, 3190
E. Ben-Ari, R. Cohen, M. Gandelman, L. J. W. Shimon, J. M. L. Martin, D. Milstein
Iron (II) complexes based on electron-rich, bulky PNN-and PNP-type ligands
Inorg. Chim. Acta 2006, 359, 1955
J. Zhang, M. Gandelman, D. Herrman, G. Leitus, L. J. W. Shimon, Y. Ben-David, D. Milstein
A general method for preparation of metal carbenes via solution-and polymer-based approaches
J. Am. Chem. Soc. 2005, 127, 15265
M. Gandelman, K. M. Naing, B. Rybtchinski, E. Poverenov, Y. Ben-David
Highly Enantioselective Catalytic Conjugate Addition of N‐Heterocycles to α, β‐Unsaturated Ketones and Imides
Angew. Chem. Int. Ed. 2005, 44, 2393
M. Gandelman, E. N. Jacobsen
Pincer “hemilabile” effect. PCN platinum (II) complexes with different amine “arm length”
Organometallics 2005, 24, 1082
E. Poverenov, M. Gandelman, L. J. W. Shimon, H. Rozenberg, Y. Ben-David, D. Milstein
Nucleophilic De‐coordination and Electrophilic Regeneration of “Hemilabile” Pincer‐Type Complexes: Formation of Anionic Dialkyl, Diaryl, and Dihydride PtII Complexes Bearing No Stabilizing π‐Acceptors
Chem.: Eur. J. 2004, 10, 4673
E. Poverenov, M. Gandelman, L. J. W. Shimon, H. Rozenberg, Y. Ben‐David, D. Milstein
Electron-rich, bulky ruthenium PNP-type complexes. Acceptorless catalytic alcohol dehydrogenation
Organometallics 2004, 23, 4026
J. Zhang, M. Gandelman, L. J. W. Shimon, H. Rozenberg, D. Milstein
C-C versus C-H Activation and versus Agostic C-C Interaction Controlled by Electron Density at the Metal Center
Chem.: Eur. J. 2003, 9, 4295
M. Gandelman, L. J. W. Shimon, D. Milstein
Interplay between Solvent and Counteranion Stabilization of Highly Unsaturated Rhodium(III) Complexes: Facile Unsaturation‐Induced Dearomatization
Chem.: Eur. J. 2003, 9, 2595
M. Gandelman, L. Konstantinovski, H. Rozenberg, D. Milstein
Metallacarbenes from diazoalkanes: an experimental and computational study of the reaction mechanism
J. Am. Chem. Soc. 2003, 125, 6532
R. Cohen, B. Rybtchinski, M. Gandelman, H. Rozenberg, J. M. L. Martin, D. Milstein
Novel Azine Reactivity: Facile N-N Bond Cleavage, C-H Activation, and N-N Coupling Mediated by RhI
Angew. Chem. Int. Ed. 2003, 42, 1949
R. Cohen, B. Rybtchinski, M. Gandelman, L. J. W. Shimon, J. M. L. Martin, D. Milstein
Selective Ortho C− H Activation of Haloarenes by an Ir (I) System
J. Am. Chem. Soc. 2003, 125, 4714
E. Ben-Ari, M. Gandelman, H. Rozenberg, L. J. W. Shimon, D. Milstein
Synthesis, Structure, and Reactivity of New Rhodium and Iridium Complexes, Bearing a Highly Electron-Donating PNP System. Iridium-Mediated Vinylic C− H Bond Activation
Organometallics 2002, 21, 812
D. Hermann, M. Gandelman, H. Rozenberg, L. J. W. Shimon, D. Milstein
A new general method for the preparation of metal carbene complexes
J. Am. Chem. Soc. 2001 123, 5372
M. Gandelman, B. Rybtchinski, N. Ashkenazi, R. M. Gauvin, D. Milstein
The first observation and kinetic evaluation of a single step metal insertion into a C− C Bond
J. Am. Chem. Soc. 2000 122, 9848
M. Gandelman, A. Vigalok, L. Konstantinovski, D. Milstein
Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C–N bond
Chem. Commun. 2000, 1603
M. Gandelman, D. Milstein
A PCN ligand system. exclusive C− C activation with rhodium (I) and C− H activation with platinum (II)
Organometallics 1997, 16, 3981
M. Gandelman, A. Vigalok, L. J. W. Shimon, D. Milstein
